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Next: Spin Angular Momentum Up: Mathematical Interlude: The Legendre Previous: The Legendre Polynomials

The Spherical Harmonics

The Spherical Harmonics, tex2html_wrap_inline4629 , that are conventionally used are:

  equation3006

which is valid for tex2html_wrap_inline5631 , while the eigenfunctions corresponding to negative values of m are obtained from:

equation3014

The functions tex2html_wrap_inline5635 are the associated Legendre polynomials defined by:

equation3016

which is valid for tex2html_wrap_inline5631 , and the values for negative m given by:

equation3018

(Remember tex2html_wrap_inline5533 ). truein


truein Problem : 11 From the above definitions of tex2html_wrap_inline4629 and tex2html_wrap_inline5645 , determine the values of tex2html_wrap_inline5647 . Write out the quantities tex2html_wrap_inline5649 in terms of the above tex2html_wrap_inline4629 (and their complex conjugates). (For example, tex2html_wrap_inline5653 where tex2html_wrap_inline5655 .) Hence show that tex2html_wrap_inline5657 is an eigenfunction of tex2html_wrap_inline5053 and tex2html_wrap_inline5661 is an eigenfunction of tex2html_wrap_inline5055 . What are their respective eigenvalues? truein
truein

When m=0, (79) simplifies to a value independent of the azimuthal angle tex2html_wrap_inline5513

equation3034

where tex2html_wrap_inline5669 are the Legendre polynomials.

At the poles tex2html_wrap_inline5671 and tex2html_wrap_inline5673 the azimuthal angle tex2html_wrap_inline5513 are indistinguishable so tex2html_wrap_inline4629 cannot depend on tex2html_wrap_inline5513 at these angles. Therefore the only non-zero spherical harmonics for these two cases has to have m=0 i.e.

equation3041

and

equation3043

Consider two arbitrary directions in space defined respectively by the angles tex2html_wrap_inline5683 and tex2html_wrap_inline5685 and call the angle between them tex2html_wrap_inline5687 . The Spherical Harmonic Addition Theorem states that

equation3045

truein


truein Problem : 12 Let tex2html_wrap_inline5689 be the distance between two points in space so that the tex2html_wrap_inline5691 direction is tex2html_wrap_inline5693 and tex2html_wrap_inline5695 direction is tex2html_wrap_inline5697 . Prove that

equation3050

where tex2html_wrap_inline5699 stands for the smaller of the two distances tex2html_wrap_inline5701 and tex2html_wrap_inline5703 , and tex2html_wrap_inline5705 is the larger of the two distances. truein


truein This result is very useful and we will apply it when we study scattering theory as well as in variational calculations for the groundstate of the Helium atom.

Note that the tex2html_wrap_inline4629 form a complete set of orthonormal functions, i.e.

equation3055

and

equation3060

This means that any function of tex2html_wrap_inline5709 and tex2html_wrap_inline5513 can be expanded as follows:

equation3066

where

equation3071

Furthermore, if tex2html_wrap_inline5713 is the angular wavefunction of some state, normalised such that

equation3076

then the tex2html_wrap_inline5715 are the probabilities that simultaneous measurement of tex2html_wrap_inline5057 and tex2html_wrap_inline5061 on the state described by tex2html_wrap_inline5713 yields tex2html_wrap_inline5723 and tex2html_wrap_inline5301 respectively.

In the Dirac notation, an arbitrary state tex2html_wrap_inline5727 can be expanded as:

equation3086

where with the help of the orthonormality condition

equation3092

we get

equation3096

These eigenstates are also complete so:

equation3100

truein


truein Problem :13 Using tex2html_wrap_inline5729 and

displaymath5731

calculate the matrix representation of tex2html_wrap_inline5733 and tex2html_wrap_inline5061 for the AM state 3/2. Check that the commutation relations hold.

truein


truein Problem :14 Given the Hamiltonian

displaymath5739

Find the eigenvalues of tex2html_wrap_inline5741 if (a) the AM of the system is 1, (b) the AM of the system is 2.

truein


truein
next up previous
Next: Spin Angular Momentum Up: Mathematical Interlude: The Legendre Previous: The Legendre Polynomials

Gunaretnam Rajagopal
Tue Oct 15 17:55:22 BST 1996