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General Case

Two arbitrary AM vectors, tex2html_wrap_inline6257 and tex2html_wrap_inline6259 have AM eigenstates are given by tex2html_wrap_inline6275 and tex2html_wrap_inline6277 , respectively. Form the total AM vector tex2html_wrap_inline6795 . We then have available, two different complete sets of commuting AM operators tex2html_wrap_inline6797 , with eigenstates tex2html_wrap_inline6799 and tex2html_wrap_inline6801 with eigenstates tex2html_wrap_inline6803 . Both sets of eigenkets form a complete orthonormal system, which implies that they can be expanded in terms of each other. For example the expansion of tex2html_wrap_inline6803 in the basis tex2html_wrap_inline6807 is:

equation4414

The (real) coefficients tex2html_wrap_inline6809 are called Clebsch-Gordon coefficients. (Note that because the z-component of the AM is conserved, the only composite states that contribute to the above sum are those for which tex2html_wrap_inline6811 ). In a commonly applied terminology, one refers to tex2html_wrap_inline6803 as an eigenfunction in the coupled representation and to tex2html_wrap_inline6815 as an eigenfunction in the the un-coupled representation. The allowed values that j can take (given tex2html_wrap_inline6279 and tex2html_wrap_inline6281 ) are

equation4452

with the possible values of m being:

equation4454

A general formula for the Clebsch-Gordon coefficients has been derived by Wigner (using Group Theory) and numerical tables of these coefficients can be found in books dealing with atomic spectroscopy.



Gunaretnam Rajagopal
Tue Oct 15 17:55:22 BST 1996