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Two arbitrary AM vectors,
and
have AM eigenstates are given by
and
, respectively. Form the total AM vector
. We then have available, two different complete sets of commuting AM operators
, with eigenstates
and
with eigenstates
. Both sets of eigenkets form a complete orthonormal system, which implies
that they can be expanded in terms of each other. For example the expansion
of
in the basis
is:
The (real) coefficients
are called Clebsch-Gordon coefficients. (Note that because the z-component
of the AM is conserved, the only composite states that contribute to the
above sum are those for which
). In a commonly applied terminology, one refers to
as an eigenfunction in the coupled representation and to
as an eigenfunction in the the un-coupled representation. The allowed values
that j can take (given
and
) are
with the possible values of m being:
A general formula for the Clebsch-Gordon coefficients has been derived by Wigner (using Group Theory) and numerical tables of these coefficients can be found in books dealing with atomic spectroscopy.